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In order to explore the influence of different activators on the structure and properties of the prepared activated carbon, bamboo fiber-based activated carbons (BFACs) were prepared by four activators of phosphoric acid, pyrophosphoric acid, zinc chloride, and diammonium biphosphate (BFAC-H₃PO₄, BFAC-H₄P₂O₇, BFAC-ZnCl₂, and BFAC-(NH₄)₂HPO₄) and BFACs adsorption performance and electrochemical properties were investigated. The main conclusions were: the specific surface area of the four BFACs varies greatly, among which BFAC-ZnCl₂ was the highest, at 1908.5074 m²/g, and BFAC-(NH₄)₂HPO₄ was the lowest, at 641.5941 m²/g. In terms of the pore structure, BFAC-H₃PO₄ and BFAC-H₄P₂O₇ are mainly mesopores and BFAC-ZnCl₂ and BFAC-(NH₄)₂HPO₄ are mainly micropores. The BFAC-ZnCl₂ sample had the largest specific capacitance, with a specific capacitance of 121.2730 F/g at a current density of 0.2 A/g, with a small internal resistance and good electrochemical reversibility and capacitance performance. The adsorption properties were better for BFAC-ZnCl₂ and BFAC-H₃PO₄ and the adsorption amounts were 648.75 and 548.75 mg/g, respectively.