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Preparation and Photovoltaic Evaluation of CuO@Zn(Al)O-Mixed Metal Oxides for Dye Sensitized Solar Cell
oleh: Mohamed Bashir Ali Bashir, Altaf Hussain Rajpar, Ethar Yahya Salih, Emad M. Ahmed
Format: | Article |
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Diterbitkan: | MDPI AG 2023-02-01 |
Deskripsi
In this manuscript, a series of dye-sensitized solar cells (DSSCs) were fabricated as a function of post-processing temperature based on mesoporous CuO@Zn(Al)O-mixed metal oxides (MMO) in conjunction with dye N719 as the main light absorber; the proposed CuO@Zn(Al)O geometry was, in turn, attained using Zn/Al-layered double hydroxide (LDH) as a precursor via combination of co-precipitation and hydrothermal techniques. In particular, the dye loading amount onto the deposited mesoporous materials was anticipated via regression equation-based UV-Vis technique analysis, which evidently demonstrated a robust correlation along with the fabricated DSSCs power conversion efficiency. In detail, of the DSSCs assembled, CuO@MMO-550 exhibited short-circuit current (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>J</mi><mrow><mi>S</mi><mi>C</mi></mrow></msub></mrow></semantics></math></inline-formula>) and open-circuit voltage (<inline-formula><math xmlns="http://www.w3.org/1998/Math/MathML" display="inline"><semantics><mrow><msub><mi>V</mi><mrow><mi>O</mi><mi>C</mi></mrow></msub></mrow></semantics></math></inline-formula>) of 3.42 (mA/cm<sup>2</sup>) and 0.67 (V) which result in significant fill factor and power conversion efficiency of 0.55% and 1.24%, respectively. This could mainly be due to the relatively high surface area of 51.27 (m<sup>2</sup>/g) which in turn validates considerable dye loading amount of 0.246 (mM/cm<sup>−2</sup>).