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Knowledge of melliferous flora has applications in areas of commercial and scientific interest because pollinators, such as different bee taxa, provide ecosystem services that include the pollination of both agroecosystems and wild ecosystems. In this manuscript, we reviewed research carried out in Mexico on the identification of melliferous flora, emphasizing the methods used and highlighting their implications for bee–plant–human interactions as well as the advantages and disadvantages of the different methods used in the determination of this type of vegetation. Methods such as observations of the foraging process, palynological analysis, and taxonomic determination via genetic sequencing were analyzed. We observed advantages in each method, but better integration between methods would facilitate concrete advances in understanding this type of flora. Ultimately, the determination of melliferous flora is a practical tool that provides useful knowledge in diverse economic and scientific sectors.