[Bis(2-pyridyl-κN)amine]chlorido(η6-hexamethylbenzene)ruthenium(II) hexafluoridophosphate dichloromethane solvate
oleh: Gajendra Gupta, Bruno Therrien, Jinkwon Kim
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-05-01 |
Deskripsi
In the title half-sandwich complex, [RuCl(η6-C12H18)(C10H9N3)]PF6·CH2Cl2, the ruthenium(II) ion is four-coordinated by a chloro, a hexamethylbenzene and a bidentate N,N′-chelating di(pyridin-2-yl)amine ligand. In the crystal, the amino N—H group forms a hydrogen bond with the chloro ligand of a neighbouring complex, thus forming chains along the b axis. Weak intermolecular C—H...F and C—H... Cl contacts are also observed.