Bis[bis(1H-benzimidazol-2-ylmethyl)amine]copper(II) dichloride methanol disolvate dihydrate
oleh: Xian-you Xia, Yong Zhang, Yuan Qu, Xue-mei Chen, Ting Liu
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-01-01 |
Deskripsi
In the title compound, [Cu(C16H14N5)2]Cl2·2CH4O·2H2O, the cationic metal complex resides on a crystallographic centre of inversion, with the Cu2+ bonded to two bis(1H-benzimidazol-2-ylmethyl)amines (IDB). The coordination geometry of the Cu2+ ion is distorted octahedral with an N6 ligand set. A three-dimensional framework structure is formed by means of hydrogen bonds and π–π interactions formed between imidazole and phenyl rings, and between phenyl and phenyl rings, with centroid-to-centroid distances of 3.690 (2)–3.977 (2) Å and interplanar spacings of 3.445 (2)–3.502 (2) Å.