Cooperative redox activation for carbon dioxide conversion

oleh: Zhong Lian, Dennis U. Nielsen, Anders T. Lindhardt, Kim Daasbjerg, Troels Skrydstrup

Format: Article
Diterbitkan: Nature Portfolio 2016-12-01

Deskripsi

While CO2 can be converted to CO for further reactivity, typically this involves the generation of large amounts of waste. Here the authors report the conversion of CO2to CO, with the siloxane by-product being further used in a carbonylative Hiyama-Denmark coupling to form diarylketones.