Bis{2-[2-(dimethylamino)ethyliminomethyl]-4,6-disulfanylphenolato}cobalt(II) monohydrate
oleh: Ying-Jie Cai, Jin Li, Peng Huang, Qing-Fu Zeng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-09-01 |
Deskripsi
In the title hydrated complex, [Co(C11H15N2OS2)2]·H2O, the CoII atom (site symmetry 2) is coordinated by two O,N,N′-tridentate Schiff base ligands, resulting in a very distorted cis-CoO2N4 octahedral geometry for the metal ion. In the crystal, the water molecule (O-atom site symmetry 2) interacts with nearby complex molecules by way of bifurcated O—H...(O,S) hydrogen bonds.