Tris(1,10-phenanthroline-κ2N,N′)iron(II) μ-oxido-bis[trichloridoferrate(III)] ethanol hemisolvate
oleh: Liu-He Wei, Yu-Na Zhang, Ming-Ming Yu, Zhan-Xian Li
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2008-12-01 |
Deskripsi
The title compound, [Fe(C12H8N2)3][Fe2Cl6O]·0.5CH3CH2OH, consists of one [Fe(phen)3]2+ cation (phen = 1,10-phenanthroline), one [Fe2Cl6O]2− anion and one half-molecule of ethanol. In the cation, the FeII atom is coordinated by six N atoms from three phen ligands in a distorted octahedral geometry. In the bent anion, two FeIII atoms are connected by a bridging oxide O atom [bridging angle = 160.6 (4)°], and each FeIII atom is also coordinated by three Cl atoms, completing a distorted tetrahedral geometry.