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In order to satisfy the corrosion resistance requirement, the original pipe material of a heat exchanger is replaced by BFe30-1-1white copper. Based on analysis of the welding characteristics, joint structure and factors affecting the welding quality of BFe30-1-1 tube-to-tubesheet, the welding procedure is made. The morphology inspection, test of pull-off strength, metallographic structure examination and hardness test of the tube-to-tubesheet joints which is welded according to the welding procedure, can satisfy the standard and design requirements. The success of the test provides a good reference for the welding quality control of white copper heat exchangers.