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Bobtraillite from Gejiu hyperagpaitic nepheline syenite, southwestern China: new occurrence and crystal structure
oleh: Y. Wang, Y. Wang, F. Nestola, Z. Hou, X. Gu, G. Dong, Z. Yang, G. Fan, Z. Xiao, K. Qu, K. Qu
Format: | Article |
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Diterbitkan: | Copernicus Publications 2023-01-01 |
Deskripsi
<p>A second occurrence of bobtraillite is described from the Gejiu nepheline syenite, southwestern China. The extremely rare and complex boron-bearing zirconium silicate is associated with albite, orthoclase, jadeite, fluorite, andradite, titanite, as well as other REE and zirconium-bearing minerals, catapleiite, moxuanxueite, låvenite, eudialyte, britholite-(Ce), and calcioancylite-(La). The EMP and LA-ICP-MS analyses of the studied material give an empirical formula: (Na<span class="inline-formula"><sub>9.70</sub></span>Li<span class="inline-formula"><sub>0.42</sub></span>K<span class="inline-formula"><sub>0.08</sub>□<sub>1.80</sub></span>)<span class="inline-formula"><sub>Σ12.00</sub></span>(Sr<span class="inline-formula"><sub>10.61</sub></span>Ca<span class="inline-formula"><sub>1.14</sub></span>Fe<span class="inline-formula"><sub>0.07</sub>□<sub>0.18</sub></span>)<span class="inline-formula"><sub>Σ12.00</sub></span>(Zr<span class="inline-formula"><sub>12.87</sub></span>Ti<span class="inline-formula"><sub>0.53</sub></span>Nb<span class="inline-formula"><sub>0.31</sub></span>REE<span class="inline-formula"><sub>0.08</sub></span>Y<span class="inline-formula"><sub>0.06</sub></span>U<span class="inline-formula"><sub>0.02</sub></span>Th<span class="inline-formula"><sub>0.01</sub>□<sub>0.12</sub></span>)<span class="inline-formula"><sub>Σ14.00</sub></span>(Si<span class="inline-formula"><sub>42.41</sub></span>B<span class="inline-formula"><sub>5.59</sub></span>Al<span class="inline-formula"><sub>0.02</sub></span>)<span class="inline-formula"><sub>Σ48.02</sub></span>O<span class="inline-formula"><sub>132</sub></span>(OH)<span class="inline-formula"><sub>12</sub></span> <span class="inline-formula"><span class="Radical">⚫</span></span> 12H<span class="inline-formula"><sub>2</sub></span>O. Bobtraillite is trigonal, with space group <span class="inline-formula"><math xmlns="http://www.w3.org/1998/Math/MathML" id="M25" display="inline" overflow="scroll" dspmath="mathml"><mrow><mi>P</mi><mover accent="true"><mn mathvariant="normal">3</mn><mo mathvariant="normal">¯</mo></mover><mi>c</mi></mrow></math><span><svg:svg xmlns:svg="http://www.w3.org/2000/svg" width="23pt" height="12pt" class="svg-formula" dspmath="mathimg" md5hash="3c1302eaea2aa69cf43c4367df4d285f"><svg:image xmlns:xlink="http://www.w3.org/1999/xlink" xlink:href="ejm-35-65-2023-ie00001.svg" width="23pt" height="12pt" src="ejm-35-65-2023-ie00001.png"/></svg:svg></span></span>1, <span class="inline-formula"><i>a</i>=19.6977(6)</span>, <span class="inline-formula"><i>c</i>=9.9770(3)</span> Å, <span class="inline-formula"><i>V</i>=3352.4(2)</span> Å<span class="inline-formula"><sup>3</sup></span>, <span class="inline-formula"><i>Z</i>=1</span>. Single-crystal structure refinement revealed that all sodium occupies the Na(1) and Na(2) sites; the site occupancy of these two positions is 0.835(18) and 0.15(2), respectively, suggesting that Na(1) site is Na dominant, while Na(2) is a vacancy-dominant site. The [8]-coordinated site has been assigned to Sr and Ca, with free occupancy factors, 0.874(10) and 0.126(10), respectively. These new data indicate that the ideal formula of bobtraillite could be written as (Na,<span class="inline-formula">□</span>)<span class="inline-formula"><sub>12</sub></span>(<span class="inline-formula">□</span>,Na)<span class="inline-formula"><sub>12</sub></span>Sr<span class="inline-formula"><sub>12</sub></span>Zr<span class="inline-formula"><sub>14</sub></span>(Si<span class="inline-formula"><sub>3</sub></span>O<span class="inline-formula"><sub>9</sub></span>)<span class="inline-formula"><sub>10</sub></span>[Si<span class="inline-formula"><sub>2</sub></span>BO<span class="inline-formula"><sub>7</sub></span>(OH)<span class="inline-formula"><sub>2</sub></span>]<span class="inline-formula"><sub>6</sub></span> <span class="inline-formula"><span class="Radical">⚫</span></span> 12H<span class="inline-formula"><sub>2</sub></span>O.</p>