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The soil-water characteristic curve is the basic constitutive relation to express the water-holding characteristics of ion-absorbed rare earth. The simulated solution mining test and pressure plate apparatus tests were carried out, the relationship between matric suction and water content under different leaching actions was obtained. Using the Fredlund and Xing four-parameter model, the soil-water characteristic curves of ion-absorbed rare earth under different leaching actions were obtained, and the changing trend of each parameter was analyzed, and the influence of different leaching methods on the water-holding characteristic of soil was obtained. For different types of leaching solutions, the water-holding capacity of the soil varies from strong to weak for pure water, the 3% magnesium sulfate solution, and the 3% ammonium sulfate solution; as the concentration of the leaching solution increases, the water-holding capacity of the sample gradually decreases, and it decreases most significantly from 0% to 2%. Moreover, the saliency of the “hysteresis effect” of the soil-water characteristic curve was from high to low for pure water, the 3% magnesium sulfate solution, and the 3% ammonium sulfate solution, and the “hysteresis effect” showed a decreasing trend with the increase in the concentration.