A Diiron Hydrogenase Mimic Featuring a 1,2,3-Triazolylidene
oleh: Andrea Mele, Simone Bertini, Martin Albrecht, Catherine Elleouet, Francois Pétillon, Philipp Schollhammer
| Format: | Article |
|---|---|
| Diterbitkan: | Swiss Chemical Society 2020-06-01 |
Deskripsi
A novel complex featuring a mesoionic carbene [Fe2(CO)5(trz)(μ-pdt)] (1) (trz = 1-phenyl-l,3-methyl,4-butyl-1,2,3-triazol-5-ylidene), was synthesized and spectroscopically and structurally characterized. The reductive behaviour of this compound in the presence and in the absence of acid (CH3CO2H) was examined by cyclic voltammetry (CV) that revealed the lack of efficient activity towards proton reduction.