Poly[1,4-bis(ammoniomethyl)cyclohexane [di-μ-bromido-dibromidoplumbate(II)]]
oleh: Matthew Kyle Rayner, David Gordon Billing
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-06-01 |
Deskripsi
The title compound, {(C8H20N2)[PbBr4]}n, crystallizes as an inorganic–organic hybrid with alternating layers of diammonium cations and two-dimensional corner-sharing PbBr6 octahedra extending parallel to the bc plane, which are eclipsed relative to one another. Both PbBr6 octahedra and the organic cation exhibit overline{1} symmetry. The cations interact via N—H...Br hydrogen bonding in the right-angled halogen sub-type of the terminal halide hydrogen-bonding motif.