Chiral Diketopyrrolopyrrole-Helicene Polymer With Efficient Red Circularly Polarized Luminescence

oleh: Kais Dhbaibi, Kais Dhbaibi, Chengshuo Shen, Chengshuo Shen, Marion Jean, Nicolas Vanthuyne, Thierry Roisnel, Marcin Górecki, Marcin Górecki, Bassem Jamoussi, Ludovic Favereau, Jeanne Crassous

Format: Article
Diterbitkan: Frontiers Media S.A. 2020-04-01

Deskripsi

Chiral diketopyrrolopyrrole (DPP)-helicene polymers were synthesized to develop efficient red circularly polarized (CP) light emitters. These original chiral dyes display intense electronic circular dichroism (ECD) and CP luminescence (CPL) in the far-red spectral region owing to the presence of excitonic coupling between achiral DPPs within the chiral environment of the polymeric structure. This work affords an interesting example illustrating the potential of π-conjugated helical polymers for chiral optoelectronic applications.