(±)-syn-Isopropyl 4-(1,1,1,3,3,3-hexafluoropropan-2-yloxy)-1-hydroxy-3-methyl-2-(prop-1-ynyl)cyclopent-2-enecarboxylate
oleh: Annika Gille, Markus Schürmann, Hans Preut, Martin Hiersemann
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-07-01 |
Deskripsi
The title compound, C16H18F6O4, was obtained through an unprecedented one-pot reaction sequence involving a Gosteli–Claisen rearrangement and a cycloisomerization. The constitution and relative configuration were determined by single-crystal X-ray diffraction analysis. In the crystal, molecules are connected via O—H ... O hydrogen bonds.