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2-Chloro-N-{3-cyano-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazol-5-yl}acetamide
oleh: Jian-qiang Zhang, Qiu He, Qiang-hua Jiang, Hai-pin Mu, Rong Wan
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2012-01-01 |
Deskripsi
The title compound, C13H6Cl3F3N4O, was synthesized by the reaction of 5-amino-1-[2,6-dichloro-4-(trifluoromethyl)phenyl]-1H-pyrazole-3-carbonitrile and 2-chloroacetyl chloride. The five-membered pyrazole ring makes a dihedral angle of 71.5 (3)° with the benzene ring. The –CF3 group is disordered by rotation, and the F atoms are split over two sets of sites with occupancies of 0.59 (2) and 0.41 (2). The crystal structure features weak C—H...O and N—H...N interactions involving the carbonyl and cyano groups as acceptors.