Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Crystal structure of bis{2-[(2-hydroxyethyl)amino]ethanol-κ3O,N,O′}copper(II) terephthalate
oleh: Ya-Ping Li, Dajun Sun, Julia Ming, Liying Han, Guan-Fang Su
Format: | Article |
---|---|
Diterbitkan: | International Union of Crystallography 2014-11-01 |
Deskripsi
The molecular components of the title salt, [Cu(C4H11NO2)2](C8H4O4), are one CuII cation O,N,O′-chelated by two tridentate 2-[(2-hydroxyethyl)amino]ethanol ligands, and a terephthalate counter-dianion, located about a centre of inversion. The complex CuII cation is located about a centre of inversion and shows typical Jahn–Teller distortion, with two short Cu—O and two short Cu—N bonds in the equatorial plane and two long Cu—O bonds to the axial atoms. The cations are arranged in sheets parallel to (100), with the centrosymmetric terephthalate anions located between the sheets. Each anion is the acceptor of four O—H...O and two N—H...O hydrogen bonds, forming a three-dimensional network structure.