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The 1.5 mm thick Cu/Al composite sheet was obtained after explosive-welding and 6 passes cold rolling. The effects of annealing temperature and time on the microstructure, mechanical properties, and conductivity of cold-rolled Cu/Al composite sheets were investigated. The results show that the thickness of the interface diffusion layer with compounds of Al _2 Cu, AlCu, and Al _4 Cu _9 increases with the increase in annealing temperature and holding time, and the total activation energy is 108 kJ mol ^−1 . The tensile strength of composite sheets decreases and the fracture elongation increases with the increase of annealing temperature. Especially when the annealing temperature increased from 300 ℃ to 350 ℃, the tensile yield strength decreased from 225 MPa to 77 MPa, and the elongation increased from 16% to 37.5%. The tensile-shear strength of composite sheets reaches to 117 MPa after annealing at 400 ℃ for 2 h. The conductivity of composite sheet is greatly affected by the annealing time. At the annealing temperature of 350 ℃ and time of 4 h, the composite sheets show a better conductivity of 96.4% IACS.