Enzyme-triggered Radical Reactions: Another Approach For Tin-free Radical Chemistry
oleh: Ibrahima Cissokho, Anne-Marie Farnet, Elisée Ferré, Michèle P. Bertrand, Gérard Gil, Stéphane Gastaldi
| Format: | Article |
|---|---|
| Diterbitkan: | Swiss Chemical Society 2012-06-01 |
Deskripsi
The system laccase/mediator/dioxygen is able to trigger radical reactions with radical precursors which are not natural substrates of this enzyme. The radical generation has been accomplished by single electron transfer oxidation of a 1,3-dicarbonyl precursor. The process is exemplified with a radical cascade.