Palladium catalyzed radical relay for the oxidative cross-coupling of quinolines

oleh: Xiaorui Zhao, Xiaojuan Zhu, Kang Wang, Junqian Lv, Shangjun Chen, Guohua Yao, Junyu Lang, Fei Lv, Yinghui Pu, Ruoou Yang, Bingsen Zhang, Zheng Jiang, Ying Wan

Format: Article
Diterbitkan: Nature Portfolio 2022-07-01

Deskripsi

Traditional approaches for transition-metal catalyzed oxidative cross-coupling reactions rely on sp 2-hybridized starting materials. Here the authors report a heterogeneous Pd-catalyzed radical relay method for the conversion of a heteroarene C(sp 3)–H bond into ethers.