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Bis(tetraphenylphosphonium) di-μ-iodido-bis[diiodidotellurate(II)]
oleh: Risto S. Laitinen, Raija Oilunkaniemi, Sari M. Närhi
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2008-12-01 |
Deskripsi
The structure of the title compound, (C24H20P)2[Te2I6], is composed of discrete PPh4+ cations and centrosymmetric [Te2I6]2− anions. The tellurium(II) atom shows a sligthly distorted square-planar TeI4 geometry and is coordinated to two bridging and two terminal iodine atoms. The planar [Te2I6]2− ions are isolated by the cations and no intermolecular tellurium–halogen or halogen–halogen interactions are present.