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catena-Poly[[diaquanickel(II)]-μ-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato]
oleh: Yun-Yun Wang, Rui-Ding Hu, Wen-Zhong Zhu, Qiu-Yue Lin
Format: | Article |
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Diterbitkan: | International Union of Crystallography 2009-07-01 |
Deskripsi
In the crystal structure of the title compound, [Ni(C8H8O5)(H2O)2]n, the NiII cation is in a Jahn–Teller-distorted octahedral coordination environment binding to two O atoms from water molecules, the bridging O atom of the bicycloheptane unit, two carboxylate O atoms from different carboxylate groups and one carboxylate O atom from a symmetry-related bridging ligand. The crystal structure is made up from layers propagating parallel to the bc plane.