Bis(triphenylphosphoranylidene)ammonium iodide
oleh: Michael A. Beckett, Peter N. Horton, Michael B. Hursthouse, James L. Timmis
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-02-01 |
Deskripsi
The title compound, C36H30NP2+·I−, was obtained accidently from crystallization of a reaction mixture containing [(Ph3P)2N]OH and B(OH)3, which was contaminated with MeI. There are two independent [(Ph3P)2N]+ cations and two I− anions within the asymmetric unit. The central PNP angles are non-linear [137.6 (2) and 134.4 (2)°] and the phenyl substituents on P centres adopt different conformations within these two cations.