Diaquadichloridomethylphenyltin(IV)–1,4,7,10,13-pentaoxacyclopentadecane (1/1)
oleh: Marzieh Vafaee, Mostafa M. Amini, Seik Weng Ng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-02-01 |
Deskripsi
The asymmetric unit of the title cocrystal, [Sn(CH3)(C6H5)Cl2(H2O)2]·C10H20O5, contains two independent formula units. The organotin molecules exhibit a six-coordinate metal atom and are linked to the crown ether molecules by water–crown ether O—H...O hydrogen bonds into a linear chain running along [101]. Each coordinated water molecule forms a pair of hydrogen bonds to the same crown ether; for the crown ether molecules, only four of the five O atoms are engaged in hydrogen-bonding interactions. The metal ions show a distorted trans-C2SnCl2O2 octahedral coordination geometry [C—Sn—C = 175.3 (1) and 178.9 (1)°].