catena-Poly[[[(2,2′-bipyridine-κ2N,N′)cobalt(II)]-μ-(E)-3,3′-(but-2-ene-2,3-diyl)dibenzoato-κ4O,O′:O′′,O′′′] hemihydrate]
oleh: Zong-Sheng Li, Seik Weng Ng
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-11-01 |
Deskripsi
The title coordination polymer, {[Co(C18H14O4)(C10H8N2)]·0.5H2O}n, features a helical polymeric chain that runs along the b axis. The Co atoms are chelated by the carboxylate groups of two 3,3′-(but-2-ene-2,3-diyl)dibenzoate ligands and the N atoms of a 2,2′-bipyridine ligand. The lattice water molecule is disordered about a center of inversion and is connected to the chain by an O—H...O hydrogen bond. The CoII atom shows a distorted octahedral coordination.