Crystal structure of bis[4-(allyloxy)-N′-(but-2-en-1-ylidene)benzohydrazidato]nickel(II)
oleh: Sultana Shakila Khan, Md. Belayet Hossain Howlader, Md. Chanmiya Sheikh, Ryuta Miyatake, Ennio Zangrando
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2023-05-01 |
Deskripsi
In the title complex, [Ni(C14H15N2O2)2], the nickel(II) atom exhibits a square-planar coordination geometry, being coordinated by two negatively charged N,O chelating ligands in a trans configuration, with the metal located on a crystallographic center of symmetry. The X-ray structural characterization showed the complex to be disordered over two orientations with refined occupancies of 0.898 (2) and 0.102 (2). The whole molecule is close to planar, the five- and six-membered rings subtending a dihedral angle of 7.5 (2)°. The crystal packing is supported by C—H...π and C—H...O interactions that form a di-periodic layered network.