Find in Library

Abstract Lithium‐Sulfur (Li‐S) batteries as the next‐generation battery system have an ultrahigh theoretical energy density. However, the limited conversion of polysulfides in sulfur cathodes deteriorates the performance of Li‐S batteries. In this study, we develop a novel titanium nitride (TiN) catalyst for sulfur cathodes via atomic layer deposition (ALD). The synthesized ALD‐TiN catalyst shows controllable ultrafine particle size (<2 nm) and uniform distribution at the nanoscale in the carbon matrix. Combined with electrochemical analysis and multiple post‐characterization techniques, ALD‐TiN demonstrates an excellent catalytic effect to facilitate the nucleation and deposition of Li2S, which effectively suppresses the dissolution and shuttle of polysulfides. The as‐prepared sulfur cathodes, with the assistance of TiN catalyst, exhibit excellent cycling performance at a high rate (4 C) and deliver 200% higher discharge capacity than the pristine Sulfur‐pristine porous carbon composite cathodes.