Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
The impact of weather patterns and related transport processes on aviation's contribution to ozone and methane concentrations from NO<sub><i>x</i></sub> emissions
oleh: S. Rosanka, S. Rosanka, C. Frömming, V. Grewe, V. Grewe
| Format: | Article |
|---|---|
| Diterbitkan: | Copernicus Publications 2020-10-01 |
Deskripsi
<p>Aviation-attributed climate impact depends on a combination of composition changes in trace gases due to emissions of carbon dioxide (<span class="inline-formula">CO<sub>2</sub></span>) and non-<span class="inline-formula">CO<sub>2</sub></span> species. Nitrogen oxides (<span class="inline-formula">NO<sub><i>x</i></sub></span> <span class="inline-formula">=</span> <span class="inline-formula">NO</span> <span class="inline-formula">+</span> <span class="inline-formula">NO<sub>2</sub></span>) emissions induce an increase in ozone (<span class="inline-formula">O<sub>3</sub></span>) and a depletion of methane (<span class="inline-formula">CH<sub>4</sub></span>), leading to a climate warming and a cooling, respectively. In contrast to <span class="inline-formula">CO<sub>2</sub></span>, non-<span class="inline-formula">CO<sub>2</sub></span> contributions to the atmospheric composition are short lived and are thus characterised by a high spatial and temporal variability. In this study, we investigate the influence of weather patterns and their related transport processes on composition changes caused by aviation-attributed <span class="inline-formula">NO<sub><i>x</i></sub></span> emissions. This is achieved by using the atmospheric chemistry model EMAC (ECHAM/MESSy). Representative weather situations were simulated in which unit <span class="inline-formula">NO<sub><i>x</i></sub></span> emissions are initialised in specific air parcels at typical flight altitudes over the North Atlantic flight sector. By explicitly calculating contributions to the <span class="inline-formula">O<sub>3</sub></span> and <span class="inline-formula">CH<sub>4</sub></span> concentrations induced by these emissions, interactions between trace gas composition changes and weather conditions along the trajectory of each air parcel are investigated. Previous studies showed a clear correlation between the prevailing weather situation at the time when the <span class="inline-formula">NO<sub><i>x</i></sub></span> emission occurs and the climate impact of the <span class="inline-formula">NO<sub><i>x</i></sub></span> emission. Here, we show that the aviation <span class="inline-formula">NO<sub><i>x</i></sub></span> contribution to ozone is characterised by the time and magnitude of its maximum and demonstrate that a high <span class="inline-formula">O<sub>3</sub></span> maximum is only possible if the maximum occurs early after the emission. Early maxima occur only if the air parcel, in which the <span class="inline-formula">NO<sub><i>x</i></sub></span> emission occurred, is transported to lower altitudes, where the chemical activity is high. This downward transport is caused by subsidence in high-pressure systems. A high ozone magnitude only occurs if the air parcel is transported downward into a region in which the ozone production is efficient. This efficiency is limited by atmospheric <span class="inline-formula">NO<sub><i>x</i></sub></span> and <span class="inline-formula">HO<sub><i>x</i></sub></span> concentrations during summer and winter, respectively. We show that a large <span class="inline-formula">CH<sub>4</sub></span> depletion is only possible if a strong formation of <span class="inline-formula">O<sub>3</sub></span> occurs due to the <span class="inline-formula">NO<sub><i>x</i></sub></span> emission and if high atmospheric <span class="inline-formula">H<sub>2</sub>O</span> concentrations are present along the air parcel's trajectory. Only air parcels, which are transported into tropical areas due to high-pressure systems, experience high concentrations of <span class="inline-formula">H<sub>2</sub>O</span> and thus a large <span class="inline-formula">CH<sub>4</sub></span> depletion. Avoiding climate-sensitive areas by rerouting aircraft flight tracks is currently computationally not feasible due to the long chemical simulations needed. The findings of this study form a basis of a better understanding of <span class="inline-formula">NO<sub><i>x</i></sub></span> climate-sensitive areas and through this will allow us to propose an alternative approach to estimate aviation's climate impact on a day-to-day basis, based on computationally cheaper meteorological simulations without computationally expensive chemistry. This comprises a step towards a climate impact assessment of individual flights, here with the contribution of aviation <span class="inline-formula">NO<sub><i>x</i></sub></span> emissions to climate change, ultimately enabling routings with a lower climate impact by avoiding climate-sensitive regions.</p>