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A decade of methane measurements at the Boknis Eck Time Series Station in Eckernförde Bay (southwestern Baltic Sea)
oleh: X. Ma, M. Sun, S. T. Lennartz, S. T. Lennartz, H. W. Bange
| Format: | Article |
|---|---|
| Diterbitkan: | Copernicus Publications 2020-07-01 |
Deskripsi
<p>Coastal areas contribute significantly to the emissions of methane (<span class="inline-formula">CH<sub>4</sub></span>) from the ocean. In order to decipher its temporal variability in the whole water column, dissolved <span class="inline-formula">CH<sub>4</sub></span> was measured on a monthly basis at the Boknis Eck Time Series Station (BE) located in Eckernförde Bay (SW Baltic Sea) from 2006 to 2017. BE has a water depth of about 28 m, and dissolved <span class="inline-formula">CH<sub>4</sub></span> was measured at six water depths ranging from 0 to 25 m. In general, <span class="inline-formula">CH<sub>4</sub></span> concentrations increased with depth, indicating a sedimentary release of <span class="inline-formula">CH<sub>4</sub></span>. Pronounced enhancement of the <span class="inline-formula">CH<sub>4</sub></span> concentrations in the bottom layer (15–25 m) was found during February, May–June and October. <span class="inline-formula">CH<sub>4</sub></span> was not correlated with Chlorophyll <span class="inline-formula"><i>a</i></span> or <span class="inline-formula">O<sub>2</sub></span> over the measurement period. Unusually high <span class="inline-formula">CH<sub>4</sub></span> concentrations (of up to 696 nM) were sporadically observed in the upper layer (0–10 m; e.g., in November 2013 and December 2014) and coincided with major Baltic inflow (MBI) events. Surface <span class="inline-formula">CH<sub>4</sub></span> concentrations were always supersaturated throughout the monitoring period, indicating that Eckernförde Bay is an intense but highly variable source of atmospheric <span class="inline-formula">CH<sub>4</sub></span>. We did not detect significant temporal trends in <span class="inline-formula">CH<sub>4</sub></span> concentrations or emissions, despite ongoing environmental changes such as warming and deoxygenation in Eckernförde Bay. Overall, the <span class="inline-formula">CH<sub>4</sub></span> variability at BE is driven by a complex interplay of various biological and physical processes.</p>