Tri-μ-sulfato-κ6O:O′-bis[aqua(1,10-phenanthroline-κ2N,N′)indium(III)] dihydrate
oleh: Fwu Ming Shen, Shie Fu Lush
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2010-10-01 |
Deskripsi
In the title dinuclear InIII compound, [In2(SO4)3(C12H8N2)2(H2O)2]·2H2O, each InIII cation is coordinated by a 1,10-phenanthroline (phen) ligand, a water molecule and three sulfate O atoms in a distorted InN2O4 octahedral geometry. Three sulfate anions bridge two InIII cations, forming the dinuclear entities. O—H...O and weak C—H...O hydrogen bonding is observed in the crystal structure. The crystal structure is further consolidated by π–π stacking between nearly parallel phen ring systems [dihedral angle = 4.2 (4)°], the centroid–centroid distance between benzene rings of adjacent phen ligands being 3.528 (9) Å.