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Anchoring N-Halo (sodium dichloroisocyanurate) on the nano-Fe3O4 surface as “chlorine reservoir”: Antibacterial properties and wastewater treatment
oleh: Ardeshir Khazaei, Negin Sarmasti, Jaber Yousefi Seyf, Zohreh Merati
Format: | Article |
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Diterbitkan: | Elsevier 2020-01-01 |
Deskripsi
A novel retrievable bifunctional magnetic nano-structure (sodium dichloroisocyanurate immobilized on the Fe3O4@SiO2@Si(CH2)3Cl surface) was synthesized. Its antibacterial performance as water disinfectant successfully evaluated. The value of Minimum Bactericidal Concentration (625 ppm) and Minimum Inhibitory Concentration (314.5 ppm) show that magnetic nano-structure is a very effective antibacterial structure against the E. coli bacteria. In addition the viability of bacteria (%) was evaluated at different contact time against magnetic nano-structure. The disinfection procedure is very clean without any residual cyanuric acid in water. In other hand, oxidizing performance of nano-structure against the azo dye (acid red-18) was evaluated which attributed to the releasing HOCl in water. Kinetic of dye removal was measured at 0.01, 0.05, 0.1, and 0.5 g of nano-structure. Reducing pH and increasing temperature leads to increased Acid Red 18 degradation. Chemical oxygen demand (COD) measurement shows the effectiveness of nano-structure in acid red-18 degradation.The nano-structure turns to be magnetically retrievable, clean disinfectant, wastewater treatment agent, and its chlorine can be regenerated simply by exposure to household bleach such as Ca(OCl)2. Keywords: Disinfection, Wast water treatment, Azo dye, Magnetic chlorine reservoir