Atom Efficient Preparation of Zinc Selenates for the Synthesis of Selenol Esters under “On Water” Conditions
oleh: Luca Sancineto, Jaqueline Pinto Vargas, Bonifacio Monti, Massimiliano Arca, Vito Lippolis, Gelson Perin, Eder Joao Lenardao, Claudio Santi
| Format: | Article |
|---|---|
| Diterbitkan: | MDPI AG 2017-06-01 |
Deskripsi
We describe here an atom efficient procedure to prepare selenol esters in good to excellent yields by reacting [(PhSe)2Zn] or [(PhSe)2Zn]TMEDA with acyl chlorides under “on water” conditions. The method is applicable to a series of aromatic and aliphatic acyl chlorides and tolerates the presence of other functionalities in the starting material.