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Highly-Tunable Crystal Structure and Physical Properties in FeSe-Based Superconductors
oleh: Kaiyao Zhou, Junjie Wang, Yanpeng Song, Liwei Guo, Jian-gang Guo
Format: | Article |
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Diterbitkan: | MDPI AG 2019-10-01 |
Deskripsi
Here, crystal structure, electronic structure, chemical substitution, pressure-dependent superconductivity, and thickness-dependent properties in FeSe-based superconductors are systemically reviewed. First, the superconductivity versus chemical substitution is reviewed, where the doping at Fe or Se sites induces different effects on the superconducting critical temperature (<i>T</i><sub>c</sub>). Meanwhile, the application of high pressure is extremely effective in enhancing <i>T</i><sub>c</sub> and simultaneously induces magnetism. Second, the intercalated-FeSe superconductors exhibit higher <i>T</i><sub>c</sub> from 30 to 46 K. Such an enhancement is mainly caused by the charge transfer from the intercalated organic and inorganic layer. Finally, the highest <i>T</i><sub>c</sub> emerging in single-unit-cell FeSe on the SrTiO<sub>3</sub> substrate is discussed, where electron-phonon coupling between FeSe and the substrate could enhance <i>T</i><sub>c</sub> to as high as 65 K or 100 K. The step-wise increment of <i>T</i><sub>c</sub> indicates that the synergic effect of carrier doping and electron-phonon coupling plays a critical role in tuning the electronic structure and superconductivity in FeSe-based superconductors.