catena-Poly[[bis(2-aminoethanesulfonato-κ2N,O)nickel(II)]-μ-1,4-bis(1H-imidazol-1-yl)benzene-κ2N3:N3′]
oleh: Jin-Biao Liu
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2011-04-01 |
Deskripsi
In the hydrothermally prepared title coordination polymer, [Ni(C2H6NO3S)2(C12H10N4)]n, the NiII ion and the 1,4-bis(1H-imidazol-1-yl)benzene ligand occupy special positions on inversion centers. The metal ion shows a slightly distorted octahedral coordination geometry, being linked to two N atoms of two 1,4-bis(imidazol-1-yl)benzene ligands and to two O and two N atoms of two chelating 2-aminoethanesulfonate ligands. The 1,4-bis(imidazol-1-yl)benzene ligands bridge symmetry-related NiII ions forming polymeric chains along the [110] direction.