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Poly[μ-aqua-bis(μ5-2,4-dichlorobenzoato)dipotassium]
oleh: Graham Smith
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2014-01-01 |
Deskripsi
In the title compound, [K2(C7H3Cl2O2)2(H2O)]n, the potassium salt of 2,4-dichlorobenzoic acid, the repeating unit in the polymeric structure consists of two identical irregular KO6Cl units related by twofold rotational symmetry, linked by a bridging water molecule lying on the twofold axis. The coordination polyhedron about the K+ ion comprises a carboxylate O atom and a Cl-atom donor from a bidentate chelate ligand interaction, four O-atom donors from a doubly bridging bidentate carboxylate O,O′-chelate interaction and the water molecule. A two-dimensional polymeric structure lying parallel to (100) is generated through a series of conjoined cyclic bridges between K+ ions and is stabilized by water–carboxylate O—H...O hydrogen-bonding interactions.