catena-Poly[[bis(μ-2-formyl-6-methoxyphenolato-1:2κ4O1,O6:O1,O2)copper(II)sodium]-μ-tetrafluoridoborate-1:1′κ2F:F′]
oleh: Yu Yang, Po Gao, Jing-Lin Yang, Hai-Ge Hou, Ting Gao
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2012-01-01 |
Deskripsi
In the title heterodinuclear complex, [CuNa(BF4)(C8H7O3)2]n, the CuII ion is four-coordinated by four O atoms of two 2-formyl-6-methoxyphenolate ligands, giving rise to a square-planar geometry. The Na+ ion is six-coordinated by four O atoms from the two ligands and two F atoms of two tetrafluoridoborate anions. The tetrafluoridoborate anion links the Na+ ions, forming a one-dimensional structure along [001]. Three F atoms of the tetrafluoridoborate anion are disordered over two sets of sites, with an occupancy ratio of 0.790 (11):0.210 (11).