Find in Library
Search millions of books, articles, and more
Indexed Open Access Databases
Polarized Raman Study of First-Order Phonons in Self-Flux Grown Single-Crystalline WTe<sub>2</sub>
oleh: Peter M. Rafailov, Dimitre Dimitrov, Daniela Kovacheva, Vera Marinova
Format: | Article |
---|---|
Diterbitkan: | MDPI AG 2024-07-01 |
Deskripsi
Bulk single crystals of WTe<sub>2</sub> were grown by the self-flux method and characterized by X-ray diffraction, polarized micro-Raman spectroscopy, and optical microscopy. All methods revealed a high crystalline quality, thus demonstrating the advantages of the growth method used as a starting base for the synthesis of high-quality 2D materials. In each main scattering configuration, we recorded a series of Raman spectra in different sample orientations achieved by rotating the sample around the incident laser beam. In addition to the well-established case of excitation along the c crystal axis, we also applied laser excitation along the a and b axes. Thus, scattering configurations were also realized in the XZ and YZ polarization planes, for which no comparative literature data have yet been established. In these experiments, two new Raman-active phonons with B<sub>2</sub> symmetry and frequencies of 89 cm<sup>−1</sup> and 122 cm<sup>−1</sup> were identified. The obtained experimental data enabled us to derive the magnitude ratios of all three tensor elements of the A<sub>1</sub> modes and to find their phase differences.