Poly[bis(1H-imidazole)(μ3-7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylato)cadmium(II)]
oleh: Na Wang, Yan-Jun Wang, Qiu-Yue Lin
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-07-01 |
Deskripsi
The title compound, [Cd(C8H8O5)(C3H4N2)2]n, was synthesized by the reaction of 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylic anhydride, cadmium acetate and imidazole. The CdII atom is seven-coordinated in a distorted pentagonal-bipyramidal configuration by five O atoms from carboxylate groups of three 7-oxabicyclo[2.2.1]heptane-2,3-dicarboxylate ligands and two N atoms from two imidazole ligands. The crystal structure is stabilized by N—H...O and C—H...O hydrogen-bonding and C—H...π interactions.