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Abstract Focusing on the Russia–Ukraine war, this paper investigates natural gas futures volatilities. Applying several hybrid GARCH and EGARCH models, which innovatively incorporate both fat-tailed distribution errors and structural breaks, we derive the following new evidence. First, our hybrid modeling approach is effective in timely capturing the natural gas futures volatility spike when tensions simmered on the Russia–Ukraine border. Second, the hybrid modeling approach is effective for not only GARCH modeling but also EGARCH modeling. Third, the volatility estimates from our hybrid models have predictive power for the volatilities of nonhybrid models. Fourth, the volatility estimates from the nonhybrid models lag behind the volatilities of our hybrid models.