Structural dynamics of a metal–organic framework induced by CO2 migration in its non-uniform porous structure
oleh: Pu Zhao, Hong Fang, Sanghamitra Mukhopadhyay, Aurelia Li, Svemir Rudić, Ian J. McPherson, Chiu C. Tang, David Fairen-Jimenez, S. C. Edman Tsang, Simon A. T. Redfern
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2019-03-01 |
Deskripsi
Metal–organic frameworks that undergo structural transitions in response to external stimuli are promising for gas storage, but the mechanisms of such dynamics are poorly understood. Here the authors show that the structural transformation of ZIF-7 is induced by CO2 migration through its non-uniform porous structure.