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The present work analyzes the thermal instability of mixed convection in a horizontal porous channel that is saturated by a shear-thinning fluid following Ellis’ rheology. The fluid layer is heated from below by a constant heat flux and cooled from above by the same heat flux. The instability of such a system is investigated by means of a small-disturbances analysis and the resulting eigenvalue problem is solved numerically by means of a shooting method. It is demonstrated that the most unstable modes on the instability threshold are those with infinite wavelength and an analytical expression for such conditions is derived from an asymptotic analysis. Results show that the non-Newtonian character of the fluid has a destabilizing role.