Diaqua(5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane)nickel(II) tetracyanidonickelate(II)
oleh: Qian Zhang, Xiao-Ping Shen, Hu Zhou
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-09-01 |
Deskripsi
In the title complex, [Ni(C16H36N4)(H2O)2][Ni(CN)4], the [Ni(teta)(H2O)2]2+ cations (teta = 5,5,7,12,12,14-hexamethyl-1,4,8,11-tetraazacyclotetradecane) and [Ni(CN)4]2− anions are arranged in an alternating fashion through electrostatic and N—H...N and O—H...N hydrogen-bonding interactions, forming a two-dimensional layered structure. Adjacent layers are linked through weak van der Waals interactions, resulting in a three-dimensional supramolecular network.