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Metal oxide (MO) based solar thermochemical H₂O (WS) and CO₂ splitting (CDS) is one of the most promising and potential-containing processes that can be used to produce H₂ and syngas (liquid fuel precursor). Several non-volatile and volatile MOs were considered redox materials for the solar-driven WS and CDS operation. Among all the examined redox materials, based on their high O² storage capacity, faster oxidation kinetics, and good stability, ceria and doped ceria materials are deemed to be one of the best alternatives for the operation of the thermochemical redox reactions associated with the WS and CDS. Pure ceria was used for solar fuel production for the first time in 2006. A review paper highlighting the work done on the ceria-based solar thermochemical redox WS and CDS cycle from 2006 until 2016 is already published elsewhere by the author. This review paper presents all the significant findings reported in applying pure ceria and doped ceria materials for the WS and CDS by research teams worldwide.