Preparation and Characterization of 2-(Methylamino) Pyridine Complex of Cu(I)
oleh: Hossein Aghabozorg, Hassan Hosseini Monfared
| Format: | Article |
|---|---|
| Diterbitkan: | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR 1995-03-01 |
Deskripsi
2-(Methylamino) pyridine (HMAP) reacts with MeLi in THF and generates the lithium salt (LiMAP). Further reaction of [Cu(TMEDS)2][CuCl2] (TMEDA=tetramethylethylenediamine) with one equivalent of this ligand in THF leads to the formation of a yellow dimeric Cu(I) complex, [Cu(MAP)]2. Analytical data, molecular weight, and magnetic susceptibility measurements, confirm the formula [Cu(MAP)]2 .