{2,2′-[5-Bromopyridine-2,3-diylbis(nitrilomethylidyne)]diphenolato}chlorido(dimethylformamide)manganese(III)
oleh: Peiwan Bai, Yongjun Zhu, Shuangming Meng, Hai Xie
| Format: | Article |
|---|---|
| Diterbitkan: | International Union of Crystallography 2009-12-01 |
Deskripsi
In the title complex, [Mn(C19H12BrN3O2)Cl(C3H7NO)], the MnIII ion is coordinated by two N and two O atoms from the tetradentate Schiff base ligand, one O atom from the dimethylformamide ligand and a Cl anion in a distorted octahedral geometry. In the crystal structure, weak intermolecular C—H...Cl hydrogen bonds link the molecules into centrosymmetric dimers with a short distance of 3.878 (3) Å between the centroids of the aromatic rings.