Exploiting racemism enhanced organic room-temperature phosphorescence to demonstrate Wallach’s rule in the lighting chiral chromophores
oleh: Xiugang Wu, Chun-Ying Huang, Deng-Gao Chen, Denghui Liu, Chichi Wu, Keh-Jiunh Chou, Bin Zhang, Yafei Wang, Yu Liu, Elise Y. Li, Weiguo Zhu, Pi-Tai Chou
| Format: | Article |
|---|---|
| Diterbitkan: | Nature Portfolio 2020-05-01 |
Deskripsi
Room temperature phosphorescence (RTP) is a topic which is currently widely studied, but a study on the correlation between types of molecular solid and RTP properties is lacking. Here the authors show that RTP is enhanced in the racemic form of axial chiral molecules due to its denser R- and S- cross packing arrangement.