An Aqueous Process for Preparing Flexible Transparent Electrodes Using Non-Oxidized Graphene/Single-Walled Carbon Nanotube Hybrid Solution

oleh: Min Jae Oh, Gi-Cheol Son, Minkook Kim, Junyoung Jeon, Yong Hyun Kim, Myungwoo Son

Format: Article
Diterbitkan: MDPI AG 2023-08-01

Deskripsi

In this study, we prepared flexible and transparent hybrid electrodes based on an aqueous solution of non-oxidized graphene and single-walled carbon nanotubes. We used a simple halogen intercalation method to obtain high-quality graphene flakes without a redox process and prepared hybrid films using aqueous solutions of graphene, single-walled carbon nanotubes, and sodium dodecyl sulfate surfactant. The hybrid films showed excellent electrode properties, such as an optical transmittance of ≥90%, a sheet resistance of ~3.5 kΩ/sq., a flexibility of up to <i>ε</i> = 3.6% ((<i>R</i>) = 1.4 mm), and a high mechanical stability, even after 10<sup>3</sup> bending cycles at <i>ε</i> = 2.0% ((<i>R</i>) = 2.5 mm). Using the hybrid electrodes, thin-film transistors (TFTs) were fabricated, which exhibited an electron mobility of ~6.7 cm<sup>2</sup> V<sup>−1</sup> s<sup>−1</sup>, a current on-off ratio of ~1.04 × 10<sup>7</sup>, and a subthreshold voltage of ~0.122 V/decade. These electrical properties are comparable with those of TFTs fabricated using Al electrodes. This suggests the possibility of customizing flexible transparent electrodes within a carbon nanomaterial system.