Novel MOF-Based Photocatalyst AgBr/AgCl@ZIF-8 with Enhanced Photocatalytic Degradation and Antibacterial Properties

oleh: Ning Liu, Jie Zhang, Yanhua Wang, Qingjun Zhu, Xuan Zhang, Jizhou Duan, Baorong Hou

Format: Article
Diterbitkan: MDPI AG 2022-06-01

Deskripsi

A novel visible light-driven AgBr/AgCl@ZIF-8 catalyst was synthesized by a simple and rapid method. The composition and structure of the photocatalyst were characterized by XRD, SEM, UV-DRS, and XPS. It could be observed that the 2-methylimidazole zinc salt (ZIF-8) exhibited the rhombic dodecahedron morphology with the AgCl and AgBr particles evenly distributed around it. The composite photocatalyst AgBr/AgCl@ZIF-8 showed good photocatalytic degradation and antibacterial properties. The degradation rate of RhB solution was 98%, with 60 min of irradiation of visible light, and almost all <i>P. aeruginosaudomonas aeruginosa</i> (<i>P. aeruginosa</i>), <i>Staphylococcus aureus</i> (<i>S. aureus</i>), and <i>Escherichia coli</i> (<i>E. coli</i>) were inactivated under the irradiation of 90 min. In addition, the prepared catalyst had excellent stability and reusability. Based on the free radical capture experiment, ·O<sub>2</sub><sup>−</sup> and h<sup>+</sup> were believed to be the main active substances, and possible photocatalytic degradation and sterilization mechanisms of AgBr/AgCl@ZIF-8 were proposed.