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Aromatic imide derivatives play a critical role in boosting the electroluminescent (EL) performance of organic light-emitting diodes (OLEDs). However, the majority of aromatic imide-based materials are limited to long wavelength emission OLEDs rather than blue emissions due to their strong electron-withdrawing characteristics. Herein, two novel polycyclic fused amide units were reported as electron acceptor to be combined with either a tetramethylcarbazole or acridine donor via a phenyl linker to generate four conventional fluorescence blue emitters of <b>BBI-4MeCz</b>, <b>BBI-DMAC</b>, <b>BSQ-4MeCz</b> and <b>BSQ-DMAC</b> for the first time. <b>BSQ-4MeCz</b> and <b>BSQ-DMAC</b> based on a BSQ unit exhibited higher thermal stability and photoluminescence quantum yields than <b>BBI-4MeCz</b> and <b>BBI-DMAC</b> based on a BBI unit due to their more planar acceptor structure. The intermolecular interactions that exist in the BSQ series materials effectively inhibit the molecular rotation and configuration relaxation, and thus allow for blue-shifted emissions. Blue OLED devices were constructed with the developed materials as emitters, and the effects of both the structure of the polycyclic fused amide acceptor and the electron donor on the EL performance were clarified. Consequently, a sky-blue OLED device based on <b>BSQ-DMAC</b> was created, with a high maximum external quantum efficiency of 4.94% and a maximum luminance of 7761 cd m⁻².