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In this work, metal-doped titanium dioxide (TiO₂) was synthesised with the aim of improving photocatalytic degradation and antimicrobial activities; TiO₂ was doped with copper (Cu) ranging from 0.1 to 1.0 wt%. The physical and chemical properties of the Cu-doped TiO₂ nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), the Brunauer–Emmett–Teller method (BET) and diffuse reflection spectroscopy (DRS). The results revealed that the anatase phase of TiO₂ was maintained well in all the Cu-doped TiO₂ samples. No significant difference in the particle sizes or the specific surface areas was caused by increasing Cu doping. However, the band gap decreased continuously from 3.20 eV for undoped TiO₂ to 3.12 eV for 1.0 wt.% Cu-doped TiO₂. In addition, the 0.1 wt.% Cu-doped TiO₂ displayed a much greater photocatalytic degradation of methylene blue (MB) and excellent antibacterial ability for <i>Escherichia coli</i> (<i>E. coli</i>) compared to undoped TiO₂. On the other hand, the high Cu doping levels had negative impacts on the surface charge of nanoparticles and charge transfer for OH• generation, resulting in decreasing MB degradation and <i>E. coli</i> photokilling for 1.0 wt.% Cu-doped TiO₂.